| 01/09/07 | Dundee United Hunt 57, Robson 83 | 2-0 | Falkirk |
| 01/09/07 | Hibernian Fletcher 1(p) | 1-0 | Inverness |
| 01/09/07 | Kilmarnock | 0-1 | Aberdeen Miller 53 |
| 01/09/07 | Rangers Boyd 37, Webster 63, Cuellar 80, Collin 82(o) | 4-0 | Gretna |
| 02/09/07 | St Mirren Miranda 74 | 1-5 | Celtic Brown 21, McDonald 24, Vennegoor of Hesselink 52, Miranda 55(o), McManus 73 |
| 03/09/07 | Motherwell | 0-2 | Hearts Kingston 23, Velicka 90 |
| 15/09/07 | Hearts Driver 12, Tall 26, Stewart 65(p), Ivaskevicius 69 | 4-2 | Rangers Cousin 48(p), Beasley 73 |
| 15/09/07 | Aberdeen Smith 64 | 1-2 | Motherwell Quinn 33, Porter 36 |
| 15/09/07 | Celtic Vennegoor of Hesselink 14, 58, Donati 40, Nakamura 55, McGuire 69(o) | 5-0 | Inverness |
| 15/09/07 | Falkirk Moutinho 46 | 1-1 | Hibernian Donaldson 4(p) |
| 15/09/07 | Gretna Skelton 90 | 1-2 | Kilmarnock Gibson 3, Jarvis 35 |
| 16/09/07 | Dundee United Hunt 37, Robertson 67 | 2-0 | St Mirren |
| 22/09/07 | Falkirk Latapy 73 | 1-0 | Motherwell |
| 22/09/07 | Gretna Cowan 13, 35, Jenkins 85 | 3-2 | Dundee United Bauben 8, Wilkie 64 |
| 22/09/07 | Inverness Wyness 63, Brewster 90 | 2-1 | Hearts Black 33(o) |
| 22/09/07 | Kilmarnock | 0-0 | St Mirren |
| 23/09/07 | Hibernian Fletcher 4, Gathuessi 40, Shiels 86 | 3-2 | Celtic McGeady 25, Caldwell 66 |
| 23/09/07 | Rangers McCulloch 45, Naismith 64, Boyd 87 | 3-0 | Aberdeen |
| 29/09/07 | Motherwell Porter 23 | 1-1 | Rangers Boyd 67(p) |
| 29/09/07 | Aberdeen Diamond 15, Smith 17 | 2-0 | Gretna |
| 29/09/07 | Celtic McDonald 6, 66, 71 | 3-0 | Dundee United |
| 29/09/07 | Hibernian Donaldson 11, 30(p), 77(p), Antoine-Curier 64 | 4-1 | Kilmarnock Nish 75 |
| 29/09/07 | Inverness Wyness 6, 53, Duncan 17, Black 31 | 4-2 | Falkirk Milne 27, Arfield 46 |
| 30/09/07 | St Mirren Corcoran 77 | 1-3 | Hearts Driver 39, Stewart 55(p), Velicka 82 |
