| 06/10/07 | Dundee United Dods 77 | 1-0 | Motherwell |
| 06/10/07 | Hearts Ksanavicius 4, Zaliukas 26, Velicka 57, Nade 67 | 4-2 | Falkirk Barrett 86, Moutinho 88 |
| 06/10/07 | Kilmarnock Koudou 0, Nish 55 | 2-2 | Inverness Ford 21(o), Cowie 60 |
| 06/10/07 | Rangers | 0-1 | Hibernian Murphy 60 |
| 07/10/07 | Aberdeen Severin 42(p), 70(p), Miller 62, 87 | 4-0 | St Mirren |
| 07/10/07 | Gretna Yantorno 36 | 1-2 | Celtic Killen 85, McDonald 90 |
| 20/10/07 | Rangers Novo 27, 78(p), Ferguson 56 | 3-0 | Celtic |
| 20/10/07 | St Mirren Mehmet 34 | 1-0 | Gretna |
| 20/10/07 | Falkirk Finnigan 1 | 1-1 | Kilmarnock Wright 9 |
| 20/10/07 | Hearts Kingston 90 | 1-3 | Dundee United Robertson 13, 24, Robson 88(p) |
| 20/10/07 | Motherwell McCormack 34, 36 | 2-1 | Hibernian Fletcher 30(p) |
| 21/10/07 | Inverness Wyness 57 | 1-2 | Aberdeen Young 7, Tokely 61(o) |
| 27/10/07 | Celtic McDonald 41, 58, 87(p) | 3-0 | Motherwell |
| 27/10/07 | Gretna | 0-4 | Inverness Wyness 1(p), Cowie 30, Wilson 72, McBain 74 |
| 27/10/07 | Hibernian | 0-1 | St Mirren Mehmet 12 |
| 27/10/07 | Kilmarnock Wales 54, Nish 71(p), Gibson 76 | 3-1 | Hearts Tall 90 |
| 28/10/07 | Dundee United Wilkie 27, Robson 53(p) | 2-1 | Rangers Cousin 50(p) |
| 28/10/07 | Aberdeen Severin 45(p) | 1-1 | Falkirk Cregg 67 |
